电磁搅拌对富Ce混合稀土合金化AZ91D组织结构的影响

Effect of Electromagnetic Stirring(EMS) on Microstructure of AZ91D Magnesium Alloy Alloyed with Ce-rich Mish Metals(MM)

  • 摘要: 用光学显微镜、扫描电镜、电子耗散能谱和X射线衍射仪研究了电磁搅拌对富Ce混合稀土(MM)合金化AZ91D镁合金组织和结构的影响。结果表明,随富Ce混合稀土加入量的增加,初生相细化,β相(Mg17Al12)的相对量降低,尺寸减小,由连续网状向分离的球粒状转变。形成的Al11MM3化合物数量增多,由主要以短棒状在晶内和晶界分布向大的针状在晶界分布过渡,甚至在晶界成簇聚集。强电磁搅拌作用下,随等温搅拌温度降低,初生相尺寸变小,其形貌由球粒状加少量的玫瑰状向类球状和多边形演变;Al11MM3以类球状和细小的针状分布于晶粒和液相中。富Ce混合稀土可显著细化晶粒,改善β相的形貌和分布,降低体积分数;改变富Ce混合稀土含量可控制Al11MM3化合物的形貌和分布。电磁搅拌可同时使初生相和第二相Al11MM3细化和球粒化。

     

    Abstract: With the help of optical microscope(OM),scanning electron microscope(SEM),energy dispersion spectrometer(EDS) and X-ray diffraction(XRD) effect of EMS on microstructure of AZ91D magnesium alloy alloyed with Ce-rich MM has been investigated in the present paper.The results showed that with the addition content of Ce-rich MM increasing primary-Mg grains are refined,the content of β(Mg17Al12) whose morphology evolves from continuous network to detached sphere decreases and its size decreases,the amount of new formed Al11MM3 increases so much that the distribution transforms form short-rod in grains and at grain boundaries to fine acicular assembling at grain boundaries in the form of cluster.Under the impact of strong EMS the lower the isothermal stirring temperature is,the finer the primary α-Mg grains are,furthermore morphology primary α-Mg evolves from sphere with a few rosette to sphere-like and polygon;and Al11MM3 distributes in grains and liquid phase in the form of sphere-like and fine acicula respectively.Ce-rich mish metals results in the refinement of grain,content decrease of β phase and morphology and distribution melioration of β phase.Morphology and distribution of Al11MM3 vary with content of Ce-rich MM.EMS makes the primary α-Mg and the second phase Al11MM3 fine and spheric.

     

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