热处理制度对14Cr1MoR+904L耐点蚀性能的分析

Analysis of Heat Treatment on Pitting Resistance of 14Cr1MoR+904L Steel

  • 摘要: 针对主材质为14Cr1MoR(H)+904L的压力容器设备,采用ASTM G48A法及ASTM 262B法分析了制造过程中904L复层在经受不同热处理制度下的耐点蚀及晶间腐蚀性能。试验结果表明:904L原始板材显微组织为孪晶状奥氏体,在ASTM G48A法腐蚀条件下点蚀速率为0.008 mm/a,晶间腐蚀速率为0.826 mm/a;904L板材在经历爆炸焊+675℃/3 h热校平后以及14Cr1MoR+904L壳体复合板在经历690℃/4 h的整体热处理后,复层904L板材显微组织无明显变化,点蚀速率基本保持不变、晶间腐蚀速率逐渐增加;设备封头处在经历950℃/1.0 h热压+920℃/1.5 h+690℃/6.0 h调质处理后,原奥氏体晶界处存在大量析出组织,腐蚀速率急剧增加,耐腐蚀能力严重下降。

     

    Abstract: ASTM G48 A and ASTM 262 B methods were employed to analyze the pitting and intergranular corrosion performance of 14Cr1MoR(H) + 904 L used for pressure vessel after 904 L experiencing different heat treatment. The results showed that the microstructure of original 904 L was twin austenitic,whose pitting and intergranular corrosion rates were 0.008 mm/a and 0.826 mm/a; the microstructure and pitting corrosion speed of 904L had no significant changes after experiencing explosive welding + 675℃/3h heat treatment and adding to 690℃/4h heat treatment for 14 Cr1MoR(H) + 904 L shell,meanwhile,the intergranular corrosion rate gradually increased. After the head experiencing the heat treatment of 950℃/1.0h + 920℃/1.5h + 690℃/6.0 h,the corrosion resistance declined seriously as the precipitation organization occured around prior austenite boundaries.

     

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