La空位掺杂对La-Ca-Sr-MnO3磁热性质的影响

Effect of Vacancies Addition on the Magnetocaloric Properties for La0.7-xCa0.28Sr0.02MnO3

  • 摘要: 用溶胶-凝胶法制备了不同空位掺杂的系列样品La0.7-xCa0.28Sr0.02MnO3,研究了La3+空位浓度对样品居里温度和磁热效应的影响。结果表明,在La位掺入少量空位(x<0.06),可以实现将样品的居里温度有效调整至室温,同时也促进了样品磁熵变的提高。当La空位掺杂x=0.06时,与未空位掺杂样品相比,居里温度由227 K提高到264 K,近室温,其磁熵变值为3.01 J·kg-1·K-1(外加磁场1 T)。该系列样品在室温附近,较低磁场下,有较强的磁制冷能力。

     

    Abstract: Polycrystalline samples of La0.7-xCa0.28Sr0.02MnO3 with different vacancies were prepared by the sol-gel technique,and the effects of the concentration of vacancies in La3+- site on the Curie temperature and magnetocaloric properties were investigated. The results show that the Curie temperature of the sample can be adjusted to room temperature effectively,while the magnetic entropy changes of the sample can be increased by La vacancies(x < 0.06). When the La vacancy is doped with x = 0.06,the Curie temperature rises from 227 K to 264 K,approximate to room temperature,and the magnetic entropy change is 3.01 J·kg-1·K-1(1T). The magnetic refrigeration capacity is strong when the samples are near room temperature and in low magnetic field.

     

/

返回文章
返回