集成电路用钽溅射靶材制备工艺研究

Research on Processing of Tantalum Target for Sputtering to LSIS

  • 摘要: 金属钽可作为集成电路中铜与硅基板的阻隔层材料,以防止铜与硅扩散生成铜硅合金影响电路性能。采用钽靶材通过物理气相沉积技术溅射钽到硅片上。靶材晶粒尺寸与织构取向影响溅射速率及溅射薄膜均匀性,要求钽靶材晶粒尺寸应小于100μm,在靶材整个厚度范围内应主要是(111)型织构。同时,为了避免薄膜存在杂质颗粒,要求钽靶材纯度不小于99.99%。本文对钽靶材电子束熔炼、锻造、轧制、热处理等关键工艺进行了系统研究,找到了一种有别于常规钽靶材生产工艺的新方法,所生产产品化学纯度、晶粒尺寸、织构等性能优良,产品成品率高,适于批量化生产。

     

    Abstract: Tantalum is used as the barrier layer in integrated circuit to prevent copper diffusing into Si layer, which results in the forming of copper silicon alloy and degrading performance of circuits. Tantalum is sputtered to si from tantalum target by method of physical vapor deposition. The grain size and texture of tantalum target can influence sputtering rate and thickness uniformity of sputtered film, so the grain size should be less than 100 μm and the texture is mainly(111) texture across the thickness.Meanwhile, purity of tantalum target should be at least 99.99% to avoid generation of particles in film. after studying systematically the key processes in manufacting of tantalum target, including electron-beam smelting, forging, rolling and heat treatment, a new manufacting technique of tantalum target which is suitable for industrialization is found, and the new product has good properties including purity, grain size and texture.

     

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