改性碳纤维增强Cu-NbC复合材料的制备及性能研究
Effect of Preparation and Properties of Modified Carbon Fibers Reinforced Cu-NbC Composites
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摘要: Cu基复合材料因其高导电、导热性以及易加工等特性被广泛应用于电气工程领域,近年来纤维、颗粒混杂增强Cu基复合材料由于能够协同强化以提升性能,已成为重要研究方向。本研究通过化学镀和粉末冶金法,制备了不同镀层表面改性碳纤维增强Cu-NbC复合材料,探讨不同体积分数的Cu、Ni镀层碳纤维对Cu-NbC复合材料显微组织、相对密度、硬度和电导率的影响。结果表明,改性碳纤维表面形成的均匀镀层有效改善了碳纤维与Cu基体的相容性,使碳纤维在复合材料中均匀分布;两种改性碳纤维增强Cu-NbC复合材料的相对密度和电导率均随着改性碳纤维体积分数的增加而降低;镀Cu碳纤维增强Cu-NbC复合材料的硬度随着改性碳纤维体积分数的增加而增大,镀Ni碳纤维增强Cu-NbC复合材料的硬度则呈现先增大后减小的变化趋势;除硬度外,镀Cu碳纤维增强Cu-NbC复合材料在其他各项性能上均优于镀Ni碳纤维增强Cu-NbC复合材料,展现出综合性能优势。Abstract: Cu-based composites are widely used in contact materials, electronic packaging materials, heat exchange materials and other fields because of their high electrical and thermal conductivity and easy processing characteristic. In recent years, particle and fiber hybrid reinforced Cu-based composites have became an important research direction in this field due to their synergic strengthening effect on enhancing the performance of Cu-based composites. In this study, carbon fiber reinforced Cu-NbC composites with different coating surface modification were prepared by a electroless plating and powder metallurgy method, and in order to explore the effects of Cu and Ni coated carbon fibers with different volume fractions on the microstructure, relative density, hardness and electrical conductivity of Cu-NbC composites. The results showed that the uniform coating formed on surface of the modified carbon fiber could effectively improve the compatibility between carbon fiber and Cu matrix and thus enable the carbon fibers evenly distributed in the composites. The relative densities and electrical conductivities of two modified carbon fiber reinforced Cu-NbC composites might decrease with the increase in fiber volume fractions. The hardness of Cu-coated carbon fiber reinforced Cu-NbC composites increased with the increase in fiber volume fraction while the hardness of Ni-coated carbon fiber reinforced Cu-NbC composites might decrease. Except for the hardness, the Cu- coated carbon fiber reinforced Cu-NbC composites outperformed the Ni-coated carbon fiber reinforced Cu-NbC composites in all other properties, showing better comprehensive performance advantages.
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