柔性可编织Ti丝/TiO2纳米多孔膜光阳极的制备及其光电催化性能研究

李梦琦, 李小龙, 顾晓栋, 沈忱思, 张丽莎

李梦琦, 李小龙, 顾晓栋, 沈忱思, 张丽莎. 柔性可编织Ti丝/TiO2纳米多孔膜光阳极的制备及其光电催化性能研究[J]. 材料开发与应用, 2023, 38(6): 67-73.
引用本文: 李梦琦, 李小龙, 顾晓栋, 沈忱思, 张丽莎. 柔性可编织Ti丝/TiO2纳米多孔膜光阳极的制备及其光电催化性能研究[J]. 材料开发与应用, 2023, 38(6): 67-73.
LI Mengqi, LI Xiaolong, GU Xiaodong, SHEN Chensi, ZHANG Lisha. Study on Preparation of Flexible Weaveable Ti Wire/TiO2 Nanoporous Film Photoanodes and Their Photocatalytic Performance[J]. Development and Application of Materials, 2023, 38(6): 67-73.
Citation: LI Mengqi, LI Xiaolong, GU Xiaodong, SHEN Chensi, ZHANG Lisha. Study on Preparation of Flexible Weaveable Ti Wire/TiO2 Nanoporous Film Photoanodes and Their Photocatalytic Performance[J]. Development and Application of Materials, 2023, 38(6): 67-73.

柔性可编织Ti丝/TiO2纳米多孔膜光阳极的制备及其光电催化性能研究

基金项目: 

上海市自然科学基金(21ZR1402500);国家重点研发计划项目(2022YFB3804905,2022YFB3804900);福州大学能源与环境光催化国家重点实验室开放课题(SKLPEE-KF202101)

详细信息
    作者简介:

    李梦琦,女,2000年生,硕士,研究方向为柔性光热和光催化材料的制备及其性能研究。E-mail:lmq2946321882@163.com

  • 中图分类号: TB333

Study on Preparation of Flexible Weaveable Ti Wire/TiO2 Nanoporous Film Photoanodes and Their Photocatalytic Performance

  • 摘要: 半导体光电催化是一种可高效降解各类污染物的技术,其关键在于开发高效、易回收且性能稳定的光阳极。利用阳极氧化法在柔性Ti丝表面原位生长TiO2纳米多孔薄膜,最终制得的薄膜孔径约为85 nm,厚度约为10 μm。Ti丝/TiO2纳米多孔膜复合物具有良好的柔性,将其编织成质量为0.25 g、面积约为36 cm2的织物光阳极,并进行光电催化实验。结果表明:光照下,随着偏压从0 V增加到0.6 V,光电流从0 mA上升至0.32 mA。在0.6 V外加电压以及可见光光照120 min后,溶液中的罗丹明B降解效率高达87.8%,明显高于光催化时的60.0%和电催化时的3.6%。循环使用4次后,光阳极仍对罗丹明B保持着85.0%的降解效率,展现了良好的稳定性。因此,Ti丝/TiO2纳米多孔膜光阳极在光电催化降解污染物上具有较好的应用前景。
    Abstract: Various pollutants can be efficiently degraded by semiconductor photoelectrocatalysis technology and the key of this technology is to develop efficient, easily recyclable and stable photoelectrodes. In this study, TiO2 nanoporous films grow in situ on the surface of the flexible titanium wire by using anodic oxidation technology, and the as-prepared films possess pore size diameters of 85 nm and thickness of 10 μm. The Ti wire/TiO2 nanofilm composite has excellent flexibility, and is woven into fabric photoanodes with the weight of 0.25 g and area of 36 cm2. The photocatalytic experiment is carried out on the fabric photoanodes. The results show that the photocurrent rises from 0 mA to 0.32 mA when the bias voltage increases from 0 V to 0.6 V under the illumination condition. It is worth noting that the fabric photoanodes can degrade 87.8% Rhodamine B (RhB) in the photo electrocatalytic process for 120 min under the bias voltage of 0.6 V, which significantly exceeds 60.0% and 3.6% of those of the photocatalysis and electrocatalysis. Furthermore, the degradation efficiency of RhB remains 85.0% after four cycles, showing good performance stability of Ti wire/TiO2 nanoporous film photoanodes. Therefore, Ti wire/TiO2 nanoporous film photoanode shows excellent prospects for photoelectroca-talytic degradation of contaminants.
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  • 期刊类型引用(1)

    1. 周守平,张同飞,陈田田,杜邦昊,李妮,姜瑞雪. TiO_2光阳极材料光-电催化降解恩诺沙星影响因素研究. 山东农业大学学报(自然科学版). 2024(04): 495-501 . 百度学术

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出版历程
  • 收稿日期:  2022-12-06
  • 网络出版日期:  2024-01-09
  • 刊出日期:  2023-12-14

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