Study on Microstructure and Properties of A New Type of Sulfuric Acid and Hydrochloric Acid Corrosion-Resistant Cold Rolled Steel
-
摘要: 以一种新型冷轧耐蚀钢为研究对象,分析了Mo、Sb等元素对实验钢的显微组织,力学性能,耐硫酸、耐盐酸腐蚀等性能的影响。结果表明:实验钢添加Mo、Sb等元素后,铁素体晶粒尺寸只有6.24 μm,屈服强度为384 MPa,抗拉强度为459 MPa,伸长率为27.5 %;在力学性能与SPA-C产品相当的基础上,实验钢在硫酸腐蚀环境下的腐蚀速率为0.14 mg/(cm2·h),在盐酸腐蚀环境下的腐蚀速率为0.31 mg/(cm2·h),实验钢的耐腐蚀性能较传统SPA-C的提升显著。Abstract: A new type of corrosion-resistant cold rolled steel is taken as the object, and the effects of Mo and Sb elements on the microstructure, mechanical properties, and sulfuric acid and hydrochloric acid resistances of the steel are investigated. The results indicate that after adding Mo and Sb elements to the experimental steel, the ferrite grain size is only 6.24 μm, the yield strength is 384 MPa, the tensile strength is 459 MPa, and the elongation is 27.5 %. The mechanical properties can meet demands by regulates for the SPA-C steel. Besides, the corrosion rate of the experimental steel in the sulfuric acid medium is 0.14 mg/(cm2·h), and that in the hydrochloric acid medium is 0.31 mg/(cm2·h). The corrosion resistance of the experimental steel promotes by 10 times than that of the SPA-C steel.
-
-
[1] 阎永京. 加热炉空气预热器管破坏原因分析及预防措施[J]. 腐蚀与防护, 2010, 31(1):89-91. [2] 钱余海, 李自刚, 杨阿娜. 低合金耐硫酸露点腐蚀钢的性能和应用[J]. 特殊钢, 2005, 26(5):30-34. [3] 王军,崔强,唐春霞.新型耐盐酸硫酸腐蚀钢板和钢带的研究概况[J].南钢科技与管理,2019(1):7-10. [4] PERELOMA E V, BAYLEY C, BOYD J D. Microstructural evolution during simulated OLAC processing of a low-carbon microalloyed steel[J]. Materials Science and Engineering:A, 1996, 210(1-2):16-24.
[5] 范跃华, 樊新民, 魏伟, 等. 高强度管线钢连续冷却转变研究[J]. 材料热处理学报, 2008, 29(3):62-65. [6] 牛见青, 江海涛, 唐荻. 钼对热轧双相钢相变规律和生产工艺的影响[J]. 热加工工艺, 2011, 40(10):57-60. [7] 田星, 朱国明, 康永林, 等. CSP流程钛微合金化高强钢的第二相粒子析出行为[J]. 工程科学学报, 2015, 37(1):42-49. [8] 程汉, 熊辉辉, 张恒华. 钼含量对含铌微合金钢组织的影响[J]. 上海金属, 2019, 41(5):42-46. [9] 黄天顺, 孔贵廷. Mo对耐火钢显微组织和力学性能的影响[J]. 热加工工艺, 2015, 44(16):56-58. [10] 马植甄, 万兰凤. Gleeble模拟热轧工艺对磷非平衡晶界偏聚的影响[J]. 钢铁, 2016, 51(2):67-71. [11] 李桂川. 退火工艺对Q195冷轧钢板组织及屈强比的影响[D]. 济南:山东大学, 2017. [12] 童明伟. 550/690 MPa级高强韧低屈强比结构钢开发及抗断能力研究[D]. 武汉:武汉科技大学, 2016. [13] 叶先祥, 周成, 张聪. 新型耐硫酸盐酸露点腐蚀钢的性能研究[J]. 腐蚀科学与防护技术, 2015, 27(2):135-140. [14] 范瑞成, 张玮琦, 王永旺, 等. 耐盐酸腐蚀的金属材料[J]. 中国锰业, 2017, 35(4):97-100. [15] SUGIMOTO K, SAWADA Y. The role of molybdenum additions to austenitic stainless steels in the inhibition of pitting in acid chloride solutions[J]. Corrosion Science, 1977, 17(5):425-445.
[16] PARK S A, KIM S H, YOO Y H, et al. Effect of chloride ions on the corrosion behavior of low-alloy steel containing copper and antimony in sulfuric acid solution[J]. Metals and Materials International, 2015, 21(3):470-478.
计量
- 文章访问数: 102
- HTML全文浏览量: 41
- PDF下载量: 12