不同压缩比下的闭孔硬质聚合物泡沫的性能研究

Properties of Closed-cell Rigid Polymeric Foams under Different Compressive Ratios

  • 摘要: 本研究以热固性聚氯乙烯(PVC)泡沫与热塑性聚对苯二甲酸乙二醇酯(PET)泡沫为研究对象,对不同压缩比下的闭孔硬质聚合物泡沫的性能演化规律进行研究。首先,采用平压实验研究了不同压缩比下的两类泡沫的外观、尺寸、密度、微观形貌等物理性能、压缩性能、准静态吸能性能;然后,讨论了压缩性能保留率与能量吸收保留率与压缩比的关系;最后,得到不同压缩比下泡沫的性能演化规律。结果表明,初始试样的泡沫压缩强度、压缩模量、准静态压缩的能量吸收等性能均与泡沫初始密度线性正相关。当压缩比为5%时,泡沫的压缩模量明显下降;当压缩比为10%和15%时,泡沫的微观结构发生了局部甚至整体破坏,压缩模量、准静态压缩的能量吸收等性能保留率显著下降;在3种压缩比时,泡沫压缩强度基本没有变化;在同一压缩比下,PET泡沫各项性能保留率均优于PVC泡沫的。本研究为泡沫及泡沫夹芯复合材料的应用提供了参考。

     

    Abstract: In this study, with the thermosetting polyvinyl chloride (PVC) foam and thermoplastic polyethylene terephthalate (PET) foam as study objects, the performance evolution rules of the closed-cell rigid polymeric foams under different compressive ratios are studied. Firstly, the physical properties such as appearance characteristics, dimensions, densities, micro-morphologies, compressive properties, and energy absorption performances of the two foams are compared. Secondly, the relationship between retention rate of compressive properties and energy absorption is discussed. Finally, the performance evolution rules of foams under different compressive ratios are obtained. According to the results, the compressive strength, compressive modulus, and energy absorption properties are linearly related to the initial density of the original sample. When the compressive ratio is lower than 5%, a significant decrease in compressive modulus is observed. When the compressive ratios are 10% and 15%, the local and even overall collapse of microstructure the foam occurs, and the compressive modulus and energy absorption decrease significantly. Under the three compressive ratios, the compressive strengths of the foams remain stable. Moreover, the retention rates of all properties mentioned for the PET foam are higher than those for the PVC foam under the same compressive ratio. This study provides references for the application of foam and foam-sandwiched composites.

     

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