喷涂距离对悬浮液等离子喷涂YSZ+Al2O3+SiC涂层组织及性能影响

Influence of Spray Distance on Microstructure and Properties of Suspension Plasma Sprayed YSZ + Al2O3 + SiC Coatings

  • 摘要: 悬浮液等离子喷涂YSZ复合陶瓷涂层因其优异的隔热性能和高温稳定性,在船舶发动机热端部件表面防护领域具有广阔应用前景,但单一YSZ涂层在苛刻工况下的硬度和耐磨性仍有不足,难以满足高盐高湿环境下长寿命服役需求。本研究采用悬浮液等离子喷涂技术在镍基高温合金表面制备了YSZ+Al2O3+SiC复合陶瓷涂层,通过分析涂层微观结构与力学性能之间的关联机制,得出喷涂距离对复合陶瓷涂层性能的影响规律。结果表明,不同喷涂距离制备的涂层均由ZrO2、Al2O3和SiC三相组成,随着喷涂距离从30 mm增至50 mm,涂层孔隙率从17.34%升至20.90%。40 mm喷涂距离制备的涂层组织结构最为均匀,综合性能最优,平均表面硬度达1 162.9HV0.2,最大截面硬度达692.0HV0.2,稳态摩擦因数约为0.33,磨损机制以磨粒磨损为主,经900 ℃熔盐腐蚀后涂层保持完整,表现出优异的抗腐蚀性能。本研究可为船舶发动机热端部件表面防护涂层的工艺优化提供理论支撑。

     

    Abstract: Suspension plasma sprayed YSZ composite ceramic coatings have broad application prospects in the surface protection of marine engine hot-end components due to their excellent thermal insulation performance and high-temperature stability. However, the hardness and wear resistance of single YSZ coating are still insufficient under harsh working conditions, making it difficult to meet the long-term service requirements in high-salt and high-humidity environments. In this study, YSZ+Al2O3+SiC composite ceramic coatings are prepared on the surface of the nickel-based superalloy using suspension plasma spraying technology. The connection between the microstructure and mechanical properties of the coating is analyzed to investigate the influence of spray distance on performances of the composite ceramic coating. The results show that the coatings prepared at different spray distances are composed of ZrO2, Al2O3 and SiC phases. As the spray distance increases from 30 mm to 50 mm, the coating porosity increases from 17.34% to 20.90%. The coating prepared at a spray distance of 40 mm has the most uniform microstructure and the best comprehensive performance, with the average surface microhardness of 1 162.9HV0.2, the maximum cross section hardness of 692.0HV0.2, and the steady-state friction coefficient of approximately 0.33. The worn mechanism is dominated by abrasive wear. The coating remains complete after 900 °C molten salt corrosion, demonstrating excellent corrosion resistance. This research can provide theoretical references for the process optimization of surface protection coatings of marine engine hot-end components.

     

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