高纯钛箔双极板单道次冲压关键参数影响规律研究

Research on the Influence Law of Key Parameters in Single Pass Stamping of High Purity Titanium Foil Bipolar Plate

  • 摘要: 钛箔具有较高的耐腐蚀性、导电性和比强度,是质子交换膜燃料电池关键性组件双极板的理想候选材料。冲压工艺是制备双极板微流道的一种高精度、高效率的加工方法,然而目前工业纯钛箔的室温单道次冲压工艺仍存在回弹和破裂等成形缺陷。针对上述问题,本研究以高纯钛箔为原料,在不同冲压速率和载荷压力下对其进行室温单道次冲压来制备双极板。结果表明,在载荷压力相同的条件下,0.003 0 mm·s-1冲压速率下流道的最大厚度减薄率最小,仅为13.05%,此时流道深度和深宽比均处在较高水平;在冲压速率相同的情况下,流道深度和深宽比随着载荷压力的增大而增大,但较高的载荷压力会导致流道最大厚度减薄率显著增大,75 kN载荷压力下可达到66.71%;当冲压速率为0.003 0 mm·s-1、载荷压力为50 kN时,高纯钛箔双极板具有较好的成形尺寸。本研究证明高纯钛箔室温单道次冲压成形工艺制造双极板具有可行性,可以为高纯钛箔双极板的工业化生产和大规模应用提供一定参考。

     

    Abstract: Titanium foil has high corrosion resistance, conductivity, and specific strength, making it an ideal candidate material for bipolar plate,the key component of proton exchange membrane fuel cells. Stamping technology is a high-precision and high-efficiency processing method for preparing bipolar plate microchannels. However, there are still forming defects such as rebound and rupture in the single pass stamping of industrial pure titanium foil at room temperature. In response to the above issues, this study uses high purity titanium foil as raw material and conducts single pass stamping at room temperature under different stamping rates and load pressures to prepare bipolar plates. The results show that under the same load pressure, the maximum thickness thinning rate of the runner is the smallest at 0.003 0 mm·s-1 stamping speed, which is only 13.05%. At this time, both the runner depth and aspect ratio are at the relatively high level. Under the same stamping rate, the runner depth and aspect ratio increase with the increase of load pressure. However, the higher load pressure will lead to significant increase of the maximum thickness thinning rate, which can reach to 66.71% under 75 kN load pressure. When the stamping rate is 0.003 0 mm·s-1 and the load pressure is 50 kN, the high purity titanium foil bipolar plate has better forming dimensions. This study demonstrates that the room temperature single pass stamping forming process for manufacturing bipolar plates with high purity titanium foil is feasible, which can provide certain references for the industrial production and large scale application of high purity titanium foil bipolar plates.

     

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