Study on Preparation and Application of Epoxy Wear-Resistant Insulating Anticorrosive Coatings
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摘要: 以双酚A树脂和腰果酚改性胺树脂为基料,添加氧化铝微粉、碳化硅、氧化铁红等耐磨防腐填料,通过试验室模拟加速试验测试,获得环氧耐磨绝缘防腐涂料。该涂料在碳钢表面附着力大于6 MPa;750 g/1 000 r条件下涂层表面磨蚀失重低于30 mg;涂层表面电阻率高于8.04×1010 Ω,绝缘性好;耐盐雾测试1 000 h后,3个样板涂层表面都未起泡、未锈蚀、未脱落;在0.01 Hz低频阻抗(|Z|0.01 Hz)条件下进行电化学交流阻抗值测试,经过1 000 h的耐盐雾性能测试后,其化学交流阻抗值由测试前的1.38×109 Ω·cm2下降为测试后的8.11×107 Ω·cm2以上,涂层具有较高的阻抗值和较好的保护性能,防腐性能良好。同时该涂料应用于嘉兴轻轨试验段轨道防腐绝缘防护,经测试该产品可使轨道电阻由裸轨的15 Ω·km增加到26.25 Ω·km,证明该产品绝缘性能优异。Abstract: The epoxy wear-resistant insulating anticorrosive coating is prepared by the laboratory simulation accelerating test with the bisphenol A resin and cardanol modified amine resin as the base material and alumina powder, silicon carbide, iron oxide red and other wear-resistant anticorrosive as fillers. The surface adhesion of the coating on carbon steel is more than 6 MPa. Under the condition of 750 g/1000 r, the abrasive weight loss of the coating surface is less than 30 mg. The coating has good insulation, the surface resistivity higher than 8.04×1010 Ω. After 1 000 h of salt spray test, the coating on the three plates has no blisters, rust and peeling off. The electrochemical impedance value test is carried out under the condition of 0.01 Hz low frequency impedance (|Z|0.01 Hz), and the electrochemical impedance value of the coating drops from 1.38×109 Ω·cm2 before the salt spray resistance test to above 8.11×107 Ω·cm2 after the test, showing that the coating has high impedance value and good protection performance. Besides, the coating is applied into the track anti-corrosion insulation protection of the test section of Jiaxing light rail, and the impedance value of the track with coating is 26.25 Ω·km while that of the track with no coating is 15 Ω·km, improving that coating has excellent insulation performance.
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Keywords:
- light rail /
- high wear resistance /
- insulation /
- application
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[1] 张全伟, 张剑飞, 李斌, 等. 有机硅改性聚酯树脂耐磨涂料的研制[J]. 现代涂料与涂装, 2019, 22(2):7-9. [2] 熊联明, 向顺成, 舒宽金. 有机硅耐磨涂料改性的研究进展[J]. 化工新型材料, 2013, 41(9):22-23. [3] WANG C J, WANG H Y, LI M L, et al. Anti-corrosion and wear resistance properties of polymer composite coatings:effect of oily functional fillers[J]. Journal of the Taiwan Institute of Chemical Engineers, 2018, 85:248-256.
[4] RAHSEPAR M, MOHEBBI F. Enhancement of the wear resistance of epoxy coating in presence of MBT-loaded mesoporous silica nanocontainers[J]. Tri-bology International, 2018, 118:148-156.
[5] 汤传贵, 靳钊, 蹇锡高. PPESK耐高温自润滑耐磨涂料的研制[J]. 涂料工业, 2012, 42(1):68-70. [6] MCCOOK N L, BURRIS D L, BOURNE G R, et al. Wear resistant solid lubricant coating made from PTFE and epoxy[J]. Tribology Letters, 2005, 18(1):119-124.
[7] 吕基成, 邹洪庆, 吴厚昌, 等. WJ-R01干膜耐磨自润滑涂料在某枪械上的应用[J]. 装备环境工程, 2007, 4(3):70-72. [8] 张心悦, 陈凯锋, 亓海霞, 等. 梯度化环氧涂层的制备与结构研究[J]. 装备环境工程, 2020, 17(5):105-111. [9] 张黎黎, 王跃平, 陈凯锋, 等. 海水淡化装置内舱碳钢防护涂层寿命预测研究[J]. 装备环境工程, 2020, 17(12):119-125. [10] 武利民, 李丹, 游波. 现代涂料配方设计[M]. 北京:化学工业出版社, 2000. [11] 伍小军, 王恩琪, 江楠. 一种高性能耐磨船用涂料的制备与研究[J]. 涂料技术与文摘, 2017, 38(7):11-15. [12] 尚峰, 周燕, 李明, 等. 改性环氧耐磨涂料的性能测定[J]. 河南化工, 2016, 33(10):21-23. [13] 肖龙, 鄢冬茂, 胥维昌. 纳米技术在耐磨涂料中的应用[J]. 现代涂料与涂装, 2017, 20(7):31-34. [14] 强军锋, 王杨勇, 井新利. 高耐磨性防腐涂料的研制[J]. 石化技术与应用, 2002, 20(2):96-98. [15] 李梁, 孙健科, 孟祥军. 钛合金的应用现状及发展前景[J]. 钛工业进展, 2004, 21(5):19-24. [16] 陈兴伟. 船舶典型结构材料电偶腐蚀行为研究[D]. 青岛:中国海洋大学, 2011. [17] 宁兴龙. 俄罗斯舰船用钛[J]. 钛工业进展, 2003, 20(6):28-31. [18] 冯丽, 蔡琦. 海洋环境下碳钢与船用钛合金的腐蚀行为研究[J]. 机械制造, 2018, 56(8):77-79. [19] 郑军林, 石绪忠. 美国舰船热喷涂技术应用进展[J]. 材料开发与应用, 2015, 30(2):94-96. [20] 张黎黎, 陈凯锋, 亓海霞, 等. 一种高性能耐磨防腐涂料、涂层及制备方法:CN110734684A. 2020-01-31. [21] 张黎黎, 陈凯锋, 梁宇, 等. 高屏蔽耐温酚醛环氧重防腐涂料的制备及性能研究[J]. 涂料工业, 2020, 50(2):38-42. [22] 张海兵, 马力, 李威力, 等. 深海牺牲阳极模拟环境电化学性能研究[J]. 材料开发与应用, 2015, 30(5):63-67. [23] 陈凯锋, 亓海霞, 张心悦, 等. 极地船舶用低温耐磨涂料的制备及性能研究[J]. 涂料工业, 2020, 50(10):27-32. [24] 何广飞, 罗旭光, 卢玉龙, 等. 地铁防杂散电流的钢轨绝缘涂层研究[J]. 现代城市轨道交通, 2020, 17(10):107-109. [25] 胡维锋. 城市轨道交通过渡电阻测试方法综述[J]. 中国科技信息, 2013, 25(23):165-168. [26] 黄文勋, 丁大鹏, 郭强, 等. 一种城市轨道交通轨地过渡电阻测试系统:CN206114776U. 2017-04-19. [27] 申君容. 轨道与结构钢筋间的过渡电阻试验方案[J]. 中国科技投资, 2017, 16(8):6-7 [28] 苏孟兴, 王晶晶, 张黎黎, 等. 一种轨道用绝缘耐磨防腐多功能涂料及其制备方法:CN112251114A. 2021-01-22. [29] 欧泽中. 浅谈地铁工程轨地过渡电阻测量及分析[J]. 城市建设理论研究(电子版), 2012(11):1-5. [30] 潘宇辉. 浅谈地铁钢轨过渡电阻的测试[J]. 技术与市场, 2011, 18(4):46-47.
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