Research on Preparation and Properties of Glass Pultrusion Profile of Fiber/Polypropylene Composite Yarn
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摘要: 以玻璃纤维/聚丙烯复合纱为原料,采用拉挤成型方式制备连续纤维增强热塑性复合材料,通过组建的拉挤试验线获得了拉挤型材试样,探究了复合纱穿纱方式、模具型腔结构、模具温度和拉挤速率对制品性能的影响,并观察其截面形态。结果表明:采用收敛式型腔结构、提高模具温度、降低拉挤速率,可有效改善玻纤/树脂间结合能力,提高纤维在制品中的分布均匀性,降低制品的孔隙率,提高其力学性能。Abstract: The continuous fiber reinforced thermoplastic resin samples were prepared by pultrusion with glass fiber/polypropylene composite yarn as raw material. The pultruded samples were obtained on the lab-designed thermoplastic pultrusion line. The influences of the threading way of composite yarn, die structure, die temperature and pultrusion rate on the properties of the samples were investigated, so was the morphology of the cross section. The results showed that by adopting convergent cavity structure, increasing mold temperature and reducing pultrusion rate, the combination between glass fiber and resin was improved, the uniform distribution of fiber in the product was promoted, the porosity decreased and the mechanical properties were improved.
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Key words:
- composite yarn /
- pultrusion die /
- porosity /
- flexural properties
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[1] 邱科礼,张晶.树脂基复合材料在海军装备中的研究进展及应用[J].硅酸盐通报,2019,38(12):3873-3877. [2] 万炳甲,王明义.玻纤增强聚丙烯复合材料研究进展[J].工程塑料应用,2019,38(12):3873-3877. [3] 陈博.我国复合材料拉挤成型技术及应用发展情况分析[J].玻璃钢,2014(4):1-12. [4] 陈柯,薛平,孙华,等.树脂基复合材料拉挤成型研究进展[J].中国塑料,2019,33(1):116-123. [5] CHO B G,MCCARTHY S P,FANUCCI J P,et al.Fiber reinforced Nylon-6 composites produced by the reaction injection pultrusion process[J].Polymer Composites,1996,17(5):673-681. [6] LUISIER A,BOURBAN P E,MANSON J A E.Reaction injection pultrusion of PA12 composites:process and modelling[J].Composites Part A:Applied Science and Manufacturing,2003,34(7):583-595. [7] 方立.连续纤维增强热塑性复合材料制备及其性能的研究[D].上海:华东理工大学,2012. [8] NOVO P J,SILVA J F,NUNES J P,et al.Pultrusion of fibre reinforced thermoplastic pre-impregnated materials[J].Composites Part B:Engineering,2016,89:328-339. [9] WIEGAND N,MAEDER E.Commingled yarn spinning for thermoplastic/glass fiber composites[J].Fibers,2017,5(3):26. [10] SURATNO B R,YE L,MAI Y W.Simulation of temperature and curing profiles in pultruded composite rods[J].Composites Science and Technology,1998,58(2):191-197. [11] 黄生江.连续玻璃纤维增强聚丙烯的两步法拉挤成型工艺研究[D].上海:华东理工大学,2012. [12] ASTROM B T,PIPES R B.A modeling approach to thermoplastic pultrusion.Ⅰ:formulation of models[J].Polymer Composites,2010,14(3):173-183. [13] ASTROM B T,PIPES R B.A modeling approach to thermoplastic pultrusion Ⅱ:verification of models[J].Polymer Composites,2010,14(3):184-194. [14] KIM D H,LEE W I,FRIEDRICH K.A model for a thermoplastic pultrusion process using commingled yarns[J].Composites Science and Technology,2001,61(8):1065-1077. [15] BABEAU A,COMAS-CARdona S,BINETRUY C,et al.Modeling of heat transfer and unsaturated flow in woven fiber reinforcements during direct injection-pultrusion process of thermoplastic composites[J].Composites Part A-Applied Science and Manufacturing,2015,77:310-318. [16] MILLER A H,DODDS N,HALE J M,et al.High speed pultrusion of thermoplastic matrix composites[J].Composites Part A-Applied Science and Manufacturing,1998,29(7):773-782. [17] 徐佩弦.高聚物流变学及其应用[M].北京:化学工业出版社,2003:49-139. [18] BIRD R B,ARMSTRONG R C,HASSAGER O.Dynamics of polymeric liquids.Vol.1:fluid mechanics[M].1987. [19] 袁满,何亚东,李锐,等.连续纤维增强热塑性复合材料熔融浸渍模型[J].塑料科技,2019,47(7):12-17.
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