An Investigation on Phase Change Property of CH3COONa·3H2O as Energy Storage Material
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摘要: 三水醋酸钠(CH3COONa·3H2O)由于潜热较高而常作为相变储能材料被众多学者研究;而其适宜的熔点,使其能适用于家用热水储能系统等。然而,三水合醋酸钠在相变过程中存在着严重的过冷和相分离的问题。本文以三水合醋酸钠作为相变基体材料,经研究、比较分别以羧甲基纤维素、明胶作为增稠剂,添加各种成核剂后的各体系的相变储能性能,从而得出羧甲基纤维素比明胶作为该体系的增稠剂的效果好得多,Na2SiO3·9H2O、Na2B4O7·10H2O的成核效果较好。Abstract: Sodium acetate trihydrate(CH3COONa·3H2O)has been focused as a phase change material because of its large latent heat of fusion which makes it attractive as a latent heat storage material.Its melting temperature makes it suitable for applications in such as solar energy storage for domestic hot water.However,two main problems with CH3COONa·3H2O are supercooling and phase segregation.Through study and comparing the energy storage property of CH3COONa·3H2O with different additives of nucleating agents and thickeners under continuously melting and thawing,it is found that carboxy methyl cellulose is better than gelatin as a thickener for CH3COONa·3H2O,while Na2SiO3·9H2O and Na2B4O7·10H2O as nucleating agents for CH3COONa·3H2O is good.
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