The Influences of Flame Retardant on Flame Resistances and Bonding Properties of Bisphenol A Epoxy Resin
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摘要: 以有机磷系阻燃剂NP1060-A、有机氮系阻燃剂YK-04、有机卤素阻燃剂四溴双酚A等3种阻燃剂分别作为双酚A型环氧树脂的阻燃剂,研究其对双酚A型环氧树脂阻燃性能和粘接性能的影响。结果表明,随着阻燃剂添加量的增加,双酚A型环氧树脂氧指数总体上呈升高趋势,初始分解温度向低温方向移动,800℃下的成炭率增加,粘接强度呈下降趋势。与其它两种阻燃剂相比,有机磷系阻燃剂NP1060-A具有最佳的阻燃性能和粘接性能,其适宜的添加量为40%,制得的双酚A型环氧树脂阻燃氧指数为32.5%,粘接强度为13.4 MPa,800℃残炭率为11.64%。Abstract: The influences of three flame retardants on the flame resistances and bonding properties of bisphenol A epoxy resin were studied, and the flame retardants were organic phosphorus flame retardant NP1060-A, organic nitrogen flame retardant YK-04, and organic halogenate flame retardant tetrabromobisphenol A. The results showed that with the increasing of filling content of flame retardant, the limited oxygen index (LOI) value generally increased, the initial decomposition temperature shifted toward the low temperature, the char yield increased at 800 ℃, and the bonding strength reduced. The organic phosphorus flame retardant NP1060-A had contributed to better flame resistances and adhesion properties than the other two flame retardants. The appropriate filling content was 40%, and under appropriate filling content, LOI and bonding strength were 32.5% and 13.4 MPa respectively, and the char yield was 11.64% at 800 ℃.
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Key words:
- bisphenol A epoxy resin /
- flame /
- bonding
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