MENG Jiawei, LÜ Yanhong, CUI Tangyin, BAI Li, XU Haisen, FANG Huiyi, WANG Peng. Effect of Calcination Conditions on Synthesis of Ultrafine ZrB2 Powder by Sol-Gel Method[J]. Development and Application of Materials, 2024, 39(3): 77-81.
Citation: MENG Jiawei, LÜ Yanhong, CUI Tangyin, BAI Li, XU Haisen, FANG Huiyi, WANG Peng. Effect of Calcination Conditions on Synthesis of Ultrafine ZrB2 Powder by Sol-Gel Method[J]. Development and Application of Materials, 2024, 39(3): 77-81.

Effect of Calcination Conditions on Synthesis of Ultrafine ZrB2 Powder by Sol-Gel Method

More Information
  • Received Date: August 10, 2023
  • Available Online: July 22, 2024
  • ZrB2-based ceramics have broad application prospects in the field of ultra-high temperature. ZrB2 powders are prepared by sol-gel method with zirconium propanol, sucrose and boric acid as Zr, C and B sources, respectively, and the effects of calcination temperature, holding time and argon flow rate on the synthesis of ZrB2 powder are studied. The results show that with the increase of calcination temperature, the content of impurity phase in the product decreases gradually, and that the content of ZrB2 phase increases gradually. Pure ZrB2 powders are obtained by holding the precursor powders with a molar ratio of 2.85∶1∶7 of B∶Zr∶C in argon atmosphere at 1 550 ℃ for 30, 60 and 120 minutes. The average grain size of ZrB2 powders calculated by Scherrer formula is much smaller than that observed by SEM, indicating that the ZrB2 powders are composed of small grains. The argon flow rate during calcination process will affect the volatilization degree of B2O3, and then affect the phase composition of the product.
  • [1]
    NISAR A, HASSAN R, AGARWAL A, et al. Ultra-high temperature ceramics:aspiration to overcome challenges in thermal protection systems[J]. Ceramics International, 2022, 48(7):8852-8881.
    [2]
    UYANNA O, NAJAFI H. Thermal protection systems for space vehicles:a review on technology development, current challenges and future prospects[J]. Acta Astronautica, 2020, 176:341-356.
    [3]
    STROOSNIJDER M F, MÉVREL R, BENNETT M J. The interaction of surface engineering and high temperature corrosion protection[J]. Materials at High Temperatures, 1994, 12(1):53-66.
    [4]
    GOLLA B R, MUKHOPADHYAY A, BASU B, et al. Review on ultra-high temperature boride ceramics[J]. Progress in Materials Science, 2020, 111:100651.
    [5]
    SONBER J K, SURI A K. Synthesis and consolidation of zirconium diboride:review[J]. Advances in Applied Ceramics, 2011, 110(6):321-334.
    [6]
    艾江,张力,郑柯.溶胶-凝胶法制备纳米硼化锆粉体的研究[J].陶瓷, 2020(2):53-59.
    [7]
    YAN Y J, HUANG Z R, DONG S M, et al. New ro-ute to synthesize ultra-fine zirconium diboride powders using inorganic-organic hybrid precursors[J]. Journal of the American Ceramic Society, 2006, 89(11):3585-3588.
    [8]
    LI R X, ZHANG Y, LOU H J, et al. Synthesis of ZrB2 nanoparticles by sol-gel method[J]. Journal of Sol-Gel Science and Technology, 2011, 58(2):580-585.
    [9]
    曹迎楠,杜爽,张海军,等.溶胶:凝胶碳热还原法制备硼化锆超细粉体[J].硅酸盐学报, 2014, 42(10):1229-1234.
    [10]
    FAHRENHOLTZ W G. The ZrB2 volatility diagram[J]. Journal of the American Ceramic Society, 2005, 88(12):3509-3512.
  • Related Articles

    [1]ZHENG Yonghong, ZHANG Xiang-dong, SHI Junhu. Preparation of CuFe2O4 Hollow Microspheres with Catalytic Activity by Sol-gel Calcinations Method[J]. Development and Application of Materials, 2012, 27(6): 39-42. DOI: 10.19515/j.cnki.1003-1545.2012.06.010
    [2]ZHOU Jun-shi, WANG Yong-an, XU Qi-ming, HAO Li-jun. Microstructure and Properties of Bi-CVG Ferrite With Low B2O3 Dopant[J]. Development and Application of Materials, 2009, 24(6): 28-32. DOI: 10.19515/j.cnki.1003-1545.2009.06.007
    [3]LIU Zhi-gang, LIU Ying-cai, CHU Lei, ZHANG Ning, DING Li-li, RONG Ding-hui. Effects of Al2O3-doping on Microstructure and Performance of ZrO2 Ceramics[J]. Development and Application of Materials, 2008, 23(6): 12-15. DOI: 10.19515/j.cnki.1003-1545.2008.06.005
    [4]WEI Yao, LI Zhen. Effect of Doping La2O3 and Y2O3 on Properties of (Na0.5Bi0.5)0.94Ba0.06TiO3 Lead-free Ceramics[J]. Development and Application of Materials, 2008, 23(4): 1-4,12. DOI: 10.19515/j.cnki.1003-1545.2008.04.001
    [5]LI Jing-ling, CHEN Wen-zhe, LIU Ming-hui, ZHANG Zhi-gang. Fabrication of Al2O3-TiO2 Nanotubes[J]. Development and Application of Materials, 2007, 22(5): 46-48,53. DOI: 10.19515/j.cnki.1003-1545.2007.05.012
    [6]XIAO Dai-hong, SONG Min, CHEN Kang-hua, CHEN Fang-quan. Microstructure and Mechanical Properties of in Situ Synthesized TiB-Nd2O3-Ti Composite by Ingot Metallurgy[J]. Development and Application of Materials, 2007, 22(2): 8-12. DOI: 10.19515/j.cnki.1003-1545.2007.02.003
    [7]XIE Yan-chun, CUI Hong-zhi, YUAN Jian-jun. Microstructures of In-situ TiB2/Al2O3 Composite Ceramic[J]. Development and Application of Materials, 2006, 21(5): 8-10,29. DOI: 10.19515/j.cnki.1003-1545.2006.05.003
    [8]LI Xue-yong, FU Ya-dong, WENG Lü-qian, SONG Shen-hua. Preparation of Magnetoelectric Powder Pb(Mg1/3Nb2/3)O3-CoFe2O4 by Liquid-packing Method[J]. Development and Application of Materials, 2006, 21(4): 24-28. DOI: 10.19515/j.cnki.1003-1545.2006.04.008
    [9]WANG Yong-chao. Microstructure and Properties of Nanometer Al2O3 Strengthened Cu-based ODS 20[J]. Development and Application of Materials, 2006, 21(3): 7-9,29. DOI: 10.19515/j.cnki.1003-1545.2006.03.003
    [10]Du Guihuan, Jin Minghui, Qu Xuejun, Zhao Xinli. Preparation of Nanosize ZnO·Al2O3 Powder by Sol-gel Method[J]. Development and Application of Materials, 2002, 17(2): 22-25. DOI: 10.19515/j.cnki.1003-1545.2002.02.008

Catalog

    Article Metrics

    Article views (138) PDF downloads (14) Cited by()
    Related

    /

    DownLoad:  Full-Size Img  PowerPoint
    Return
    Return